英语翻译
todirectlyaffectthereactionextent,whichtakesplaceatthe
liquid-solidinterface.Indirectly,alargergasflowratehastwo
effects:(i)itcanincreasethemasstransferratebetweengas
andliquid(i.e.,higherconversion),and(ii)itreducesthe
volumetricfractionofliquid,causinglargerliquidvelocities,
thenlowerliquid/solidcontacttime(i.e.,asmallerconversion).
Thefirsteffectisnegligible,unlesstheliquidflowrateislarge,
requiringacomparativelylargetransferratefromthegas.Soon
aftertheminimumgasflowrate,thesecondeffectprevailsall
thetime.Weconcludethatlargergasflowratesalmostalways
causealowerconversion.
H2alwaysincreasestheH2O2degradation.Overall,bothpaths
candecomposeupto20%oftheH2O2available,atthelow
0.5%molconcentration,withaminimum>1%atthehighest
flowrates.Thesevaluesprovideanupperboundforthe
synthesis,giventhatH2O2isgraduallyproducedalongthebed.
Hydrogenationaccountsforapproximately1/3ofthetotal
degradation,suggestingthatsynthesiscanbeviable,ifitsrate
canbesufficientlyhigherthanthesignificantdegradation
processes.