字典翻译 问答 小学 英语 【APchemistry的一道题目Step1:N2H2O2N2HO2-+H+(fastequilibrium)Step2:N2HO2-N2O+OH-(slow)Step3:H++OH-H2O(fast)Nitramide,N2H2O2,decomposesslowlyinaqueoussolution.Thisdecompositionisbelievedtooccura】
问题标题:
【APchemistry的一道题目Step1:N2H2O2N2HO2-+H+(fastequilibrium)Step2:N2HO2-N2O+OH-(slow)Step3:H++OH-H2O(fast)Nitramide,N2H2O2,decomposesslowlyinaqueoussolution.Thisdecompositionisbelievedtooccura】
问题描述:

APchemistry的一道题目

Step1:N2H2O2N2HO2-+H+(fastequilibrium)

Step2:N2HO2-N2O+OH-(slow)

Step3:H++OH-H2O(fast)

Nitramide,N2H2O2,decomposesslowlyinaqueoussolution.Thisdecompositionisbelievedtooccuraccordingtothereactionmechanismabove.Theratelawforthedecompositionofnitramidethatisconsistentwiththismechanismisgivenbywhichofthefollowing?

(A)Rate=k[N2H2O2]

(B)Rate=k[N2H2O2][H+]

(C)Rate=k[N2H2O2]/[H+]

(D)Rate=k[N2H2O2]/[N2HO2-]

(E)Rate=k[N2H2O2][OH-]

Answer:C

请具体讲一讲为什么选C啊?

苗明回答:
  Theratelawisdeterminedinthiscasebytheslowestreactionstep:   rate=k[N2HO2-]   Equilibriumforstepbeforethesloweststep:   K=[N2HO2-][H+]/[N2H2O2]   K[N2H2O2]/[H+]=[N2HO2-]   rate=k{K[N2H2O2]/[H+]}   rate=(k1)[N2H2O2]/[H+]
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